Synthesis of 3-stannyl and 3-silyl propargyl phosphanes and the formation of a phosphinoallene

The group 14 chloropropargyls R3ECCCH2Cl (R3E = Bu3Sn, Ph3Sn, Me2PhSi, iPr3Si, nPr3Si, nBu3Si), obtained by a modified literature procedure, react with LiPPh2 to afford the novel propargyl phosphanes Ph2PCH2CCER3 in high yield, as viscous oils; (Me3Si)2PCH2CCSiPhMe2 is similarly obtained from LiP(SiMe3)2. In contrast, the reaction of PhCCCH2MgCl with ClP(NEt2)2 fails to produce a comparable propargyl phosphane, but generates preferentially (>70%) the novel phosphinoallene (Et2N)2PC(Ph)=C=CH2, which is characterised spectroscopically, and through its reaction with HCl. The coordination chemistry of representative phosphanes is explored with respect to platinum and palladium for the first time

The complexities of failing (Social Work) students - a workshop for practice educators of Social Work students held at the University of Lincoln on Thursday 27th November 2014

This workshop for practice educators teaching social work students whilst on placement explored issues relating to failing students. Reasons why students might experience difficulties whilst on placement, early identification of problems, barriers to making a fail decision and resolution of concerns were discussed. The session considered how to evidence and articulate concerns in relation to HCPC Guidance on Conduct and Ethics for Students and the appropriate PCF levels and how to develop appropriate intervention plans, using the University's concerns process or Fitness to Practise procedures where necessary

Porous weirs for flood mitigation

[Abstract]: Porous weirs offer an alternative design that could be adopted for flood mitigation. The aim of this project is to construct and simulate a 1:25 scale model of a porous weir in the wide flume of the USQ hydraulics laboratory. The goal is to determine a relationship between upstream storage (depth) and the discharge of the weir to be use in being able to determine the flood mitigation potential of the porous weir. The flow through the porous weir is to be analysed by analogy to the Darcy type equations and open channel flow equations. When the depth of flow exceeds the height of the weir an attempt will be made to fit a general weir type equation to the measured data. Results have shown that turbulent flow exists in the model and that the traditional Darcy equation does not fit the flow through the weir. However a good relationship was found by analogy to the general equation of gradually varied flow when the flow was through the porous media. Once the flow exceeded the height of the weir it was found that the flow closely resembled the flow of a traditional hard weir

Phytoremediation of Heavy-Metals-Contaminated Soils:A Short-Term Trial Involving Two Willow Species from Gloucester WillowBank in the UK

Phytoremediation, as a bioremediation process in which plants are used to remove contaminants from an environment, has proved to be a practical and low-cost strategy for recovering mining-affected areas. This study aims to assess the potential for use in phytoremediation of two willow species, Salix viminalis and Salix dasyclados, by testing their potential for cleaning-up a range of soils with differing heavy metal concentrations: Pb (111, 141, 192 and 249 mg /kg), Zn (778.6, 1482, 2734 and 4411 mg/kg) and Cd (3.00, 5.03, 9.14 and 16.07 mg/kg). The extracted metals were preferentially translocated to the leaves with considerably higher concentrations and relative BAFs in the case of S. viminalis. The highest recorded Zn concentration of over 0.5% was found in the leaves of S. viminalis growing in soil 4. However, under the conditions of the experiments, S. dasyclados showed greater potential for use in phytoremediation, especially if coupled with use of biomass for energy production. An assessment of the suitability of willow species in this role, with regard to wider aspects involved, such as use of resultant biomass and/or waste management, revealed good potential. Willows are fast growing, grow vigorously from coppiced stumps and have extensive root systems. Therefore, their use in bioenergy production through pyrolysis or combustion, coupled with flue gas screening, is strongly advised

The role of feed-forward and feedback processes for closed-loop prosthesis control

<p>Abstract</p> <p>Background</p> <p>It is widely believed that both feed-forward and feed-back mechanisms are required for successful object manipulation. Open-loop upper-limb prosthesis wearers receive no tactile feedback, which may be the cause of their limited dexterity and compromised grip force control. In this paper we ask whether observed prosthesis control impairments are due to lack of feedback or due to inadequate feed-forward control.</p> <p>Methods</p> <p>Healthy subjects were fitted with a closed-loop robotic hand and instructed to grasp and lift objects of different weights as we recorded trajectories and force profiles. We conducted three experiments under different feed-forward and feed-back configurations to elucidate the role of tactile feedback (i) in ideal conditions, (ii) under sensory deprivation, and (iii) under feed-forward uncertainty.</p> <p>Results</p> <p>(i) We found that subjects formed economical grasps in ideal conditions. (ii) To our surprise, this ability was preserved even when visual and tactile feedback were removed. (iii) When we introduced uncertainty into the hand controller performance degraded significantly in the absence of either visual or tactile feedback. Greatest performance was achieved when both sources of feedback were present.</p> <p>Conclusions</p> <p>We have introduced a novel method to understand the cognitive processes underlying grasping and lifting. We have shown quantitatively that tactile feedback can significantly improve performance in the presence of feed-forward uncertainty. However, our results indicate that feed-forward and feed-back mechanisms serve complementary roles, suggesting that to improve on the state-of-the-art in prosthetic hands we must develop prostheses that empower users to correct for the inevitable uncertainty in their feed-forward control.</p

Symmetry groupoids and patterns of synchrony in coupled cell networks

A coupled cell system is a network of dynamical systems, or “cells,” coupled together. Such systems can be represented schematically by a directed graph whose nodes correspond to cells and whose edges represent couplings. A symmetry of a coupled cell system is a permutation of the cells that preserves all internal dynamics and all couplings. Symmetry can lead to patterns of synchronized cells, rotating waves, multirhythms, and synchronized chaos. We ask whether symmetry is the only mechanism that can create such states in a coupled cell system and show that it is not. The key idea is to replace the symmetry group by the symmetry groupoid, which encodes information about the input sets of cells. (The input set of a cell consists of that cell and all cells connected to that cell.) The admissible vector fields for a given graph—the dynamical systems with the corresponding internal dynamics and couplings—are precisely those that are equivariant under the symmetry groupoid. A pattern of synchrony is “robust” if it arises for all admissible vector fields. The first main result shows that robust patterns of synchrony (invariance of “polydiagonal” subspaces under all admissible vector fields) are equivalent to the combinatorial condition that an equivalence relation on cells is “balanced.” The second main result shows that admissible vector fields restricted to polydiagonal subspaces are themselves admissible vector fields for a new coupled cell network, the “quotient network.” The existence of quotient networks has surprising implications for synchronous dynamics in coupled cell systems

Energy Efficient Servers

Computer scienc